the main subcritical wet oxidation operating parameters: Mineralis

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selecting the pressure-temperature combination

For a given type of sludge, temperature conditions will have a marked impact on COD removal efficiency (figure 47). Figure 48 highlights the fact that, with most sludge, there will be a 20 to 40 % COD removal improvement when the temperature is increased from 220 °C to 300 °C (subject to the same reaction time) and that, by working within this temperature range, the efficiency differential between the various sludges will be minor.

As in the case of any chemical reaction, oxidation kinetics rise with the temperature; however, oxygen solubility also increases by approximately 150 % when the temperature rises from 250 °C to 350 °C (figure 49) and, consequently, the transfer potential increase also causes these reaction kinetics to increase significantly.

Finally, when the law of Gay-Lussac is applied to the system, we have :

Formula: law of Gay-Lussac

Therefore, for a given O2 flow rate (i.e. a quantity of processed OM), the greater the pressure increase, the lower the amount of water that is evaporated (good for energy consumption). All these reasons explain why we decided to operate in the region of 300 °C with most sludge when using the Mineralis process.

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Figure 47. COD removal efficiency
Efficiency various sludgesSecured image
Figure 48. Efficiency differential of removed COD between the various sludges
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Figure 49. Relative solubility of oxygen depending on temperature

selecting the oxidizing agent

In order to oxidiSe the organic matter contained in sludge, we can use a whole range of powerful oxidants (hydrogen peroxide, ozone, pure oxygen). However, on grounds of cost, we only use air and oxygen.

Nevertheless, using air creates three major restrictions:

  • the system has to operate under a total pressure in the reactor that is higher than if pure oxygen is used;
  • this method creates a far higher output of permanent gases (nitrogen ballast) with the associated danger of thermal NOx production;
  • its compression consumes a large amount of electricity combined with equally high compressor maintenance costs.

This explains why recent developments systematically use O2 which has also been selected for the Mineralis process.

catalysts

Catalytic processes can be used to reduce the operating temperature inside a wet oxidation reactor. Metal catalysts (Cu SO4) must be mixed in with the effluent to be processed before it penetrates into the reactor.

However, we see no value in using this type of catalyst that creates costs that cannot be ignored and that generates a mineral by-product with a high metal content that can restrict its subsequent re-use.

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